

Does the presence of Perkin’s mauve relate to trade delays between Europe and Australia? Or was this precious fabric woven decades earlier and kept for the special purpose of a wedding. 1885 Australian made wedding gown is curious.

Perkin’s mauve, an extremely historically significant dye, was produced for less than ten years starting in 1859. The c.1865 dress containing methyl violet just four years after its initial synthesis suggests that the new synthetic dyes were embraced quite rapidly by the textile dye trade and the fashion world of the day. The analysis of these dyes revealed important information for conservators and curators of fashion, raising interesting observations and questions. This enhancement enables very small quantities of the separated dye molecules to be identified. The electromagnetic (EM) field incident on the silver nano- aggregates is greatly enhanced at the junction between nano particles resulting in a very large enhancement (> 10 4) in the Raman scattering signal of the dye molecules adsorbed there. Molecules of the separated dye are transferred onto the silver nano particles resulting in an enhanced Raman scattering signal and dye identification.Īpplication of a silver colloid to the TLC bands results in the transfer of some dye molecules to the surfaces of the silver nano particles. In this work we investigated the purple coloration of three 19 th century English dresses and one Australian wedding gown using a combination of thin layer chromatography (TLC) and surface enhanced Raman spectroscopy (SERS).įig.

The identification of specific dyestuffs on textiles, especially when only small amounts of sample are available, is challenging due to a number of complexities including contamination and decomposition.

One of the breakthroughs in textile coloration achieved during the 19 th century was the development of synthetic dyestuffs and in particular those with the colour purple.
